This paper introduces the methodology of perceptive categories through which an empirical analysis of skill is achievable, taking European Bronze Age metalworking as a case study. Based on scientific data provided by the material sciences, in this case compositional and metallographic analyses of Late Copper Age and Early Bronze Age axes, the thresholds to categorise and interpret these data, and organise them in a chaîne opératoire, are centred on the human senses-and thus on metalworking as a craft. This is a pragmatic approach that appreciates scientific measurements of metal objects as essential empirical evidence whilst recognising that a considerable share of these archaeometric data are inapt or too detailed for an understanding of skill. This empirical approach towards skill is relevant to our knowledge of the role of crafts and materials in the past. After all, skill is a fundamental asset for the production of material culture, and a distinct human-material relationship characterised by an intimate form of material engagement.