Matthew S Sigman (MatthewS Sigman)

ORCID

Publication Activity (10 Years)

Years Active: 2017-2024
Publications (10 Years): 127

Top Venues

Journal of the American Chemical Society

Chemical science

Accounts of chemical research

ACS catalysis

This page only lists publications with an associated author ORCID identifier.

Publications

G Logan Bartholomew, Samantha L Kraus, Lucas J Karas, Filippo Carpaneto, Raffeal Bennett, Matthew S Sigman, Charles S Yeung, Richmond Sarpong
14 N to 15 N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing. Journal of the American Chemical Society (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society (2024)
G Logan Bartholomew, Samantha L Kraus, Lucas J Karas, Filippo Carpaneto, Raffeal Bennett, Matthew S Sigman, Charles S Yeung, Richmond Sarpong
14 N to 15 N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing. Journal of the American Chemical Society 146 (5) (2024)
Hongyuan Sheng, Jingwen Sun, Oliver Rodríguez, Benjamin B Hoar, Weitong Zhang, Danlei Xiang, Tianhua Tang, Avijit Hazra, Daniel S Min, Abigail G Doyle, Matthew S Sigman, Cyrille Costentin, Quanquan Gu, Joaquín Rodríguez-López, Chong Liu
Autonomous closed-loop mechanistic investigation of molecular electrochemistry via automation. Nature communications 15 (1) (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society 146 (12) (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society 146 (12) (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society 146 (12) (2024)
Mohammad H Samha, Lucas José Karas, David B Vogt, Emmanuel C Odogwu, Jennifer Elward, Jennifer M Crawford, Janelle E Steves, Matthew S Sigman
Predicting success in Cu-catalyzed C-N coupling reactions using data science. Science advances 10 (3) (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society (2024)
Kaibo Feng, Elaine Reichert Raguram, James R Howard, Ellyn Peters, Cecilia Liu, Matthew S Sigman, Stephen L Buchwald
Development of a Deactivation-Resistant Dialkylbiarylphosphine Ligand for Pd-Catalyzed Arylation of Secondary Amines. Journal of the American Chemical Society (2024)
Mohammad H Samha, Lucas José Karas, David B Vogt, Emmanuel C Odogwu, Jennifer Elward, Jennifer M Crawford, Janelle E Steves, Matthew S Sigman
Predicting success in Cu-catalyzed C-N coupling reactions using data science. Science advances 10 (3) (2024)
Andrii Varenikov, Mark Gandelman, Matthew S Sigman
Development of Modular Nitrenium Bipolar Electrolytes for Possible Applications in Symmetric Redox Flow Batteries. Journal of the American Chemical Society 146 (28) (2024)
Hongyuan Sheng, Jingwen Sun, Oliver Rodríguez, Benjamin B Hoar, Weitong Zhang, Danlei Xiang, Tianhua Tang, Avijit Hazra, Daniel S Min, Abigail G Doyle, Matthew S Sigman, Cyrille Costentin, Quanquan Gu, Joaquín Rodríguez-López, Chong Liu
Autonomous closed-loop mechanistic investigation of molecular electrochemistry via automation. Nature communications 15 (1) (2024)
Andrii Varenikov, Mark Gandelman, Matthew S Sigman
Development of Modular Nitrenium Bipolar Electrolytes for Possible Applications in Symmetric Redox Flow Batteries. Journal of the American Chemical Society (2024)
Brittany C Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody C Guo, Thomas C Malig, Jacob Werth, Haiming Zhang, F Dean Toste, Francis Gosselin, Scott J Miller, Matthew S Sigman
Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical Society 146 (12) (2024)
Ambadi Thody Sabareesan, Hanna D Clements, Hamid Baniasadi, Andrew S Lyon, Matthew S Sigman, Michael K Rosen
Small-molecule properties define partitioning into biomolecular condensates. Nature chemistry (2024)
Timothy P McFadden, Reid B Cope, Rachel Muhlestein, Dustin J Layton, Jacob J Lessard, Jeffrey S Moore, Matthew S Sigman
Using Data Science Tools to Reveal and Understand Subtle Relationships of Inhibitor Structure in Frontal Ring-Opening Metathesis Polymerization. Journal of the American Chemical Society (2024)
Yang Gao, Baiyang Jiang, Nathan C Friede, Arianne C Hunter, Dylan G Boucher, Shelley D Minteer, Matthew S Sigman, Sarah E Reisman, Phil S Baran
Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, and Mechanism. Journal of the American Chemical Society 146 (7) (2024)
Hongyuan Sheng, Jingwen Sun, Oliver Rodríguez, Benjamin B Hoar, Weitong Zhang, Danlei Xiang, Tianhua Tang, Avijit Hazra, Daniel S Min, Abigail G Doyle, Matthew S Sigman, Cyrille Costentin, Quanquan Gu, Joaquín Rodríguez-López, Chong Liu
Autonomous closed-loop mechanistic investigation of molecular electrochemistry via automation. Nature communications 15 (1) (2024)
Yang Gao, Baiyang Jiang, Nathan C Friede, Arianne C Hunter, Dylan G Boucher, Shelley D Minteer, Matthew S Sigman, Sarah E Reisman, Phil S Baran
Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, and Mechanism. Journal of the American Chemical Society (2024)
Mohammad H Samha, Lucas José Karas, David B Vogt, Emmanuel C Odogwu, Jennifer Elward, Jennifer M Crawford, Janelle E Steves, Matthew S Sigman
Predicting success in Cu-catalyzed C-N coupling reactions using data science. Science advances 10 (3) (2024)
Tianhua Tang, Avijit Hazra, Daniel S Min, Wendy L Williams, Eli Jones, Abigail G Doyle, Matthew S Sigman
Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques. Journal of the American Chemical Society (2023)
Lucas W Souza, Beck R Miller, Ryan C Cammarota, Anna Lo, Ixchel Lopez, Yuan-Shin Shiue, Benjamin D Bergstrom, Sarah N Dishman, James C Fettinger, Matthew S Sigman, Jared T Shaw
Deconvoluting Nonlinear Catalyst-Substrate Effects in the Intramolecular Dirhodium-Catalyzed C-H Insertion of Donor/Donor Carbenes Using Data Science Tools. ACS catalysis 14 (1) (2023)
Adam R Pancoast, Sara L McCormack, Shelby Galinat, Ryan Walser-Kuntz, Brianna M Jett, Melanie S Sanford, Matthew S Sigman
Data science enabled discovery of a highly soluble 2,2'-bipyrimidine anolyte for application in a flow battery. Chemical science 14 (47) (2023)
Lucas W Souza, Beck R Miller, Ryan C Cammarota, Anna Lo, Ixchel Lopez, Yuan-Shin Shiue, Benjamin D Bergstrom, Sarah N Dishman, James C Fettinger, Matthew S Sigman, Jared T Shaw
Deconvoluting Nonlinear Catalyst-Substrate Effects in the Intramolecular Dirhodium-Catalyzed C-H Insertion of Donor/Donor Carbenes Using Data Science Tools. ACS catalysis 14 (1) (2023)
Jonas Rein, Soren D Rozema, Olivia C Langner, Samson B Zacate, Melissa A Hardy, Juno C Siu, Brandon Q Mercado, Matthew S Sigman, Scott J Miller, Song Lin
Generality-oriented optimization of enantioselective aminoxyl radical catalysis. Science (New York, N.Y.) 380 (6646) (2023)
Priyanka Raghavan, Brittany C Haas, Madeline E Ruos, Jules Schleinitz, Abigail G Doyle, Sarah E Reisman, Matthew S Sigman, Connor W Coley
Dataset Design for Building Models of Chemical Reactivity. ACS central science 9 (12) (2023)
Jonas Rein, Jonathan M Meinhardt, Julie L Hofstra, Matthew S Sigman, Song Lin
A Physical Organic Approach towards Statistical Modeling of Tetrazole and Azide Decomposition. Angewandte Chemie (International ed. in English) (2023)
Hanna D Clements, Autumn R Flynn, Bryce T Nicholls, Daria Grosheva, Sarah J Lefave, Morgan T Merriman, Todd K Hyster, Matthew S Sigman
Using Data Science for Mechanistic Insights and Selectivity Predictions in a Non-Natural Biocatalytic Reaction. Journal of the American Chemical Society (2023)
Lucy van Dijk, Brittany C Haas, Ngiap-Kie Lim, Kyle Clagg, Jordan J Dotson, Sean M Treacy, Katarzyna A Piechowicz, Vladislav A Roytman, Haiming Zhang, F Dean Toste, Scott J Miller, Francis Gosselin, Matthew S Sigman
Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides. Journal of the American Chemical Society (2023)
Ryan Walser-Kuntz, Yichao Yan, Matthew S Sigman, Melanie S Sanford
A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries. Accounts of chemical research (2023)
Lucas W Souza, Beck R Miller, Ryan C Cammarota, Anna Lo, Ixchel Lopez, Yuan-Shin Shiue, Benjamin D Bergstrom, Sarah N Dishman, James C Fettinger, Matthew S Sigman, Jared T Shaw
Deconvoluting Nonlinear Catalyst-Substrate Effects in the Intramolecular Dirhodium-Catalyzed C-H Insertion of Donor/Donor Carbenes Using Data Science Tools. ACS catalysis 14 (1) (2023)
Ryan Walser-Kuntz, Yichao Yan, Matthew S Sigman, Melanie S Sanford
A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries. Accounts of chemical research (2023)
Ryan Walser-Kuntz, Yichao Yan, Matthew S Sigman, Melanie S Sanford
A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries. Accounts of chemical research 56 (10) (2023)
Ryan Walser-Kuntz, Yichao Yan, Matthew S Sigman, Melanie S Sanford
A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries. Accounts of chemical research (2023)
Jonas Rein, Soren D Rozema, Olivia C Langner, Samson B Zacate, Melissa A Hardy, Juno C Siu, Brandon Q Mercado, Matthew S Sigman, Scott J Miller, Song Lin
Generality-oriented optimization of enantioselective aminoxyl radical catalysis. Science (New York, N.Y.) 380 (6646) (2023)
Priyanka Raghavan, Brittany C Haas, Madeline E Ruos, Jules Schleinitz, Abigail G Doyle, Sarah E Reisman, Matthew S Sigman, Connor W Coley
Dataset Design for Building Models of Chemical Reactivity. ACS central science 9 (12) (2023)
Tobias Morack, Tyler E Myers, Lucas José Karas, Melissa A Hardy, Brandon Q Mercado, Matthew S Sigman, Scott J Miller
An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization. Journal of the American Chemical Society (2023)
Jordan J Dotson, Lucy van Dijk, Jacob C Timmerman, Samantha Grosslight, Richard C Walroth, Francis Gosselin, Kurt Püntener, Kyle A Mack, Matthew S Sigman
Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society 145 (1) (2022)
Mohammad H Samha, Julie L H Wahlman, Jacquelyne A Read, Jacob Werth, Eric N Jacobsen, Matthew S Sigman
Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. ACS catalysis 12 (24) (2022)
Mohammad H Samha, Julie L H Wahlman, Jacquelyne A Read, Jacob Werth, Eric N Jacobsen, Matthew S Sigman
Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. ACS catalysis 12 (24) (2022)
Tobias Gensch, Gabriel Dos Passos Gomes, Pascal Friederich, Ellyn Peters, Théophile Gaudin, Robert Pollice, Kjell Jorner, AkshatKumar Nigam, Michael Lindner-D'Addario, Matthew S Sigman, Alán Aspuru-Guzik
A Comprehensive Discovery Platform for Organophosphorus Ligands for Catalysis. Journal of the American Chemical Society 144 (3) (2022)
Samantha P Kelly, Vikram V Shende, Autumn R Flynn, Qingyun Dan, Ying Ye, Janet L Smith, Sachiko Tsukamoto, Matthew S Sigman, David H Sherman
Data Science-Driven Analysis of Substrate-Permissive Diketopiperazine Reverse Prenyltransferase NotF: Applications in Protein Engineering and Cascade Biocatalytic Synthesis of (-)-Eurotiumin A. Journal of the American Chemical Society 144 (42) (2022)
Mohammad H Samha, Julie L H Wahlman, Jacquelyne A Read, Jacob Werth, Eric N Jacobsen, Matthew S Sigman
Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. ACS catalysis 12 (24) (2022)
Mohammad H Samha, Julie L H Wahlman, Jacquelyne A Read, Jacob Werth, Eric N Jacobsen, Matthew S Sigman
Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. ACS catalysis 12 (24) (2022)
Jordan J Dotson, Lucy van Dijk, Jacob C Timmerman, Samantha Grosslight, Richard C Walroth, Francis Gosselin, Kurt Püntener, Kyle A Mack, Matthew S Sigman
Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society 145 (1) (2022)
Brittany C Haas, Adam E Goetz, Ana Bahamonde, J Christopher McWilliams, Matthew S Sigman
Predicting relative efficiency of amide bond formation using multivariate linear regression. Proceedings of the National Academy of Sciences of the United States of America 119 (16) (2022)
Sepand K Nistanaki, Chloe G Williams, Benjamin Wigman, Jonathan J Wong, Brittany C Haas, Stasik Popov, Jacob Werth, Matthew S Sigman, Kendall N Houk, Hosea M Nelson
Catalytic asymmetric C-H insertion reactions of vinyl carbocations. Science (New York, N.Y.) 378 (6624) (2022)
Jordan J Dotson, Lucy van Dijk, Jacob C Timmerman, Samantha Grosslight, Richard C Walroth, Francis Gosselin, Kurt Püntener, Kyle A Mack, Matthew S Sigman
Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society (2022)
Ryan C Cammarota, Wenbin Liu, John Bacsa, Huw M L Davies, Matthew S Sigman
Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions. Journal of the American Chemical Society 144 (4) (2022)
Samer Gnaim, Adriano Bauer, Hai-Jun Zhang, Longrui Chen, Cara Gannett, Christian A Malapit, David E Hill, David Vogt, Tianhua Tang, Ryan A Daley, Wei Hao, Rui Zeng, Mathilde Quertenmont, Wesley D Beck, Elya Kandahari, Julien C Vantourout, Pierre-Georges Echeverria, Hector D Abruna, Donna G Blackmond, Shelley D Minteer, Sarah E Reisman, Matthew S Sigman, Phil S Baran
Cobalt-electrocatalytic HAT for functionalization of unsaturated C-C bonds. Nature 605 (7911) (2022)
Yannick T Boni, Ryan C Cammarota, Kuangbiao Liao, Matthew S Sigman, Huw M L Davies
Leveraging Regio- and Stereoselective C(sp 3 )-H Functionalization of Silyl Ethers to Train a Logistic Regression Classification Model for Predicting Site-Selectivity Bias. Journal of the American Chemical Society 144 (34) (2022)
Jie Xu, Samantha Grosslight, Kyle A Mack, Sierra C Nguyen, Kyle Clagg, Ngiap-Kie Lim, Jacob C Timmerman, Jeff Shen, Nicholas A White, Lauren E Sirois, Chong Han, Haiming Zhang, Matthew S Sigman, Francis Gosselin
Atroposelective Negishi Coupling Optimization Guided by Multivariate Linear Regression Analysis: Asymmetric Synthesis of KRAS G12C Covalent Inhibitor GDC-6036. Journal of the American Chemical Society 144 (45) (2022)
Tianhua Tang, Eli Jones, Thérèse Wild, Avijit Hazra, Shelley D Minteer, Matthew S Sigman
Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques. Journal of the American Chemical Society 144 (43) (2022)
Eve Y Xu, Jacob Werth, Casey B Roos, Andrew J Bendelsmith, Matthew S Sigman, Robert R Knowles
Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides. Journal of the American Chemical Society 144 (41) (2022)
Jordan J Dotson, Lucy van Dijk, Jacob C Timmerman, Samantha Grosslight, Richard C Walroth, Francis Gosselin, Kurt Püntener, Kyle A Mack, Matthew S Sigman
Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society 145 (1) (2022)
Yichao Yan, Sophia G Robinson, Thomas P Vaid, Matthew S Sigman, Melanie S Sanford
Simultaneously Enhancing the Redox Potential and Stability of Multi-Redox Organic Catholytes by Incorporating Cyclopropenium Substituents. Journal of the American Chemical Society 143 (33) (2021)
Samuel H Newman-Stonebraker, Sleight R Smith, Julia E Borowski, Ellyn Peters, Tobias Gensch, Heather C Johnson, Matthew S Sigman, Abigail G Doyle
Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis. Science (New York, N.Y.) 374 (6565) (2021)
Heather J Kulik, Matthew S Sigman
Advancing Discovery in Chemistry with Artificial Intelligence: From Reaction Outcomes to New Materials and Catalysts. Accounts of chemical research 54 (10) (2021)
Travis J DeLano, Sara E Dibrell, Caitlin R Lacker, Adam R Pancoast, Kelsey E Poremba, Leah Cleary, Matthew S Sigman, Sarah E Reisman
Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides. Chemical science 12 (22) (2021)
Jeremy D Griffin, Adam R Pancoast, Matthew S Sigman
Interrogation of 2,2'-Bipyrimidines as Low-Potential Two-Electron Electrolytes. Journal of the American Chemical Society 143 (2) (2021)
Melodie Christensen, Lars P E Yunker, Folarin Adedeji, Florian Häse, Loïc M Roch, Tobias Gensch, Gabriel Dos Passos Gomes, Tara Zepel, Matthew S Sigman, Alán Aspuru-Guzik, Jason E Hein
Data-science driven autonomous process optimization. Communications chemistry 4 (1) (2021)
Tianhua Tang, Christopher Sandford, Shelley D Minteer, Matthew S Sigman
Analyzing mechanisms in Co(i) redox catalysis using a pattern recognition platform. Chemical science 12 (13) (2021)
James B C Mack, John D Gipson, Justin Du Bois, Matthew S Sigman
Correction to "Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives". Journal of the American Chemical Society 143 (7) (2021)
Samantha L Kraus, Sean P Ross, Matthew S Sigman
Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck Reaction. Organic letters 23 (7) (2021)
Jordan J Dotson, Eric V Anslyn, Matthew S Sigman
A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters. Journal of the American Chemical Society 143 (45) (2021)
Daniel Zell, Cian Kingston, Janis Jermaks, Sleight R Smith, Natalie Seeger, Jana Wassmer, Lauren E Sirois, Chong Han, Haiming Zhang, Matthew S Sigman, Francis Gosselin
Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings. Journal of the American Chemical Society 143 (45) (2021)
Balu D Dherange, Patrick Q Kelly, Jordan P Liles, Matthew S Sigman, Mark D Levin
Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines. Journal of the American Chemical Society 143 (30) (2021)
Jennifer M Crawford, Cian Kingston, F Dean Toste, Matthew S Sigman
Data Science Meets Physical Organic Chemistry. Accounts of chemical research (2021)
Melodie Christensen, Lars P E Yunker, Folarin Adedeji, Florian Häse, Loïc M Roch, Tobias Gensch, Gabriel Dos Passos Gomes, Tara Zepel, Matthew S Sigman, Alán Aspuru-Guzik, Jason E Hein
Data-science driven autonomous process optimization. Communications chemistry 4 (1) (2021)
Wendy L Williams, Lingyu Zeng, Tobias Gensch, Matthew S Sigman, Abigail G Doyle, Eric V Anslyn
The Evolution of Data-Driven Modeling in Organic Chemistry. ACS central science 7 (10) (2021)
Sarah E Reisman, Richmond Sarpong, Matthew S Sigman, Tehshik P Yoon
Organic Chemistry: A Call to Action for Diversity and Inclusion. The Journal of organic chemistry 85 (16) (2020)
Jacob Werth, Matthew S Sigman
Connecting and Analyzing Enantioselective Bifunctional Hydrogen Bond Donor Catalysis Using Data Science Tools. Journal of the American Chemical Society 142 (38) (2020)
Sean P Ross, Ajara A Rahman, Matthew S Sigman
Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction. Journal of the American Chemical Society 142 (23) (2020)
Sophia G Robinson, James B C Mack, Sara N Alektiar, Justin Du Bois, Matthew S Sigman
Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine Derivatives in Aqueous Acid. Organic letters 22 (18) (2020)
Jordan De Jesus Silva, Marco A B Ferreira, Alexey Fedorov, Matthew S Sigman, Christophe Copéret
Molecular-level insight in supported olefin metathesis catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis. Chemical science 11 (26) (2020)
Anthony R Rosales, Sean P Ross, Paul Helquist, Per-Ola Norrby, Matthew S Sigman, Olaf G Wiest
Transition State Force Field for the Asymmetric Redox-Relay Heck Reaction. Journal of the American Chemical Society 142 (21) (2020)
Mark D Levin, John M Ovian, Jacquelyne A Read, Matthew S Sigman, Eric N Jacobsen
Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides. Journal of the American Chemical Society 142 (35) (2020)
Sarah E Reisman, Richmond Sarpong, Matthew S Sigman, Tehshik P Yoon
Organic Chemistry: A Call to Action for Diversity and Inclusion. Organic letters 22 (16) (2020)
Sophia G Robinson, Matthew S Sigman
Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding. Accounts of chemical research 53 (2) (2020)
Sophia G Robinson, Xiangyu Wu, Binyang Jiang, Matthew S Sigman, Song Lin
Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for Enantioselective [3 + 2] Cycloaddition. Journal of the American Chemical Society 142 (43) (2020)
Cheng-Che Tsai, Christopher Sandford, Tao Wu, Buyun Chen, Matthew S Sigman, F Dean Toste
Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling. Angewandte Chemie (International ed. in English) 59 (34) (2020)
Javier Miró, Tobias Gensch, Mario Ellwart, Seo-Jung Han, Hsin-Hui Lin, Matthew S Sigman, F Dean Toste
Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts. Journal of the American Chemical Society 142 (13) (2020)
Alec H Christian, Shang Jia, Wendy Cao, Patricia Z Musacchio, Arismel Tena Meza, Matthew S Sigman, Christopher J Chang, F Dean Toste
A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation. Journal of the American Chemical Society 141 (32) (2019)
Jolene P Reid, Rupert S J Proctor, Matthew S Sigman, Robert J Phipps
Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines. Journal of the American Chemical Society 141 (48) (2019)
Yongseok Kwon, Junqi Li, Jolene P Reid, Jennifer M Crawford, Roxane Jacob, Matthew S Sigman, F Dean Toste, Scott J Miller
Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration. Journal of the American Chemical Society 141 (16) (2019)
Christopher Sandford, Lydia R Fries, Tyler E Ball, Shelley D Minteer, Matthew S Sigman
Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization. Journal of the American Chemical Society 141 (47) (2019)
James B C Mack, Katherine L Walker, Sophia G Robinson, Richard N Zare, Matthew S Sigman, Robert M Waymouth, Justin Du Bois
Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest. Journal of the American Chemical Society 141 (2) (2019)
Jamie R Allen, Ana Bahamonde, Yukino Furukawa, Matthew S Sigman
Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction". Journal of the American Chemical Society 141 (31) (2019)
David P Hickey, Christopher Sandford, Zayn Rhodes, Tobias Gensch, Lydia R Fries, Matthew S Sigman, Shelley D Minteer
Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates. Journal of the American Chemical Society 141 (3) (2019)
Jamie R Allen, Ana Bahamonde, Yukino Furukawa, Matthew S Sigman
Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction. Journal of the American Chemical Society 141 (22) (2019)
Sophia G Robinson, Yichao Yan, Koen H Hendriks, Melanie S Sanford, Matthew S Sigman
Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes. Journal of the American Chemical Society 141 (26) (2019)
Jianbo Liu, Qianjia Yuan, F Dean Toste, Matthew S Sigman
Enantioselective construction of remote tertiary carbon-fluorine bonds. Nature chemistry 11 (8) (2019)
David P Hickey, Christopher Sandford, Zayn Rhodes, Tobias Gensch, Lydia R Fries, Matthew S Sigman, Shelley D Minteer
Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates". Journal of the American Chemical Society 141 (38) (2019)
Christopher Sandford, Martin Andrew Edwards, Kevin J Klunder, David P Hickey, Min Li, Koushik Barman, Matthew S Sigman, Henry Sheldon White, Shelley D Minteer
A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms. Chemical science 10 (26) (2019)
Marco Antonio Barbosa Ferreira, Jordan De Jesus Silva, Samantha Grosslight, Alexey Fedorov, Matthew S Sigman, Christophe Copéret
Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis. Journal of the American Chemical Society 141 (27) (2019)
Rachel M Vaden, Katrin P Guillen, Justin M Salvant, Celine B Santiago, Joseph B Gibbons, Satya S Pathi, Sasi Arunachalam, Matthew S Sigman, Ryan E Looper, Bryan E Welm
A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A. ACS chemical biology 14 (1) (2019)
Ana Bahamonde, Buthainah Al Rifaie, Victor Martín-Heras, Jamie R Allen, Matthew S Sigman
Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines. Journal of the American Chemical Society 141 (22) (2019)
Haley Albright, Paul S Riehl, Christopher C McAtee, Jolene P Reid, Jacob R Ludwig, Lindsey A Karp, Paul M Zimmerman, Matthew S Sigman, Corinna S Schindler
Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles. Journal of the American Chemical Society 141 (4) (2019)
Zhi-Min Chen, Jianbo Liu, Jing-Yao Guo, Maximilian N Loch, Ryan J DeLuca, Matthew S Sigman
Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives. Chemical science 10 (30) (2019)

Matthew S Sigman.css-eqlu8i{font-size:small;padding-left:4px;} (MatthewS Sigman)

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Matthew S Sigman (MatthewS Sigman)